Ryder Cup points are up for grabs with all the Europeans hoping for a fast start on this race
Grand Slam record-breakers Novak Djokovic and Rafael Nadal were placed on an Olympics second-round collision course in the draw for the Paris Games on Thursday.
Nadal, a singles gold medallist at the 2008 Olympics, is playing in his final Games having also won doubles gold in Rio in 2016, while Djokovic was a bronze medallist in singles in 2008.
Serbia's Djokovic, a 24-time Grand Slam champion and top seed in Paris following the withdrawal of world number one Jannik Sinner, begins his campaign against Australia's Matthew Ebden.
"I am excited for this duel in the second round, and I will give it my all," said Djokovic, who has faced Nadal 59 times over the past 18 years.
"I am aware of the importance of the Olympic Games. I represent my country, which is more responsibility and even more pressure."
Spain's Nadal, who has won 14 of his 22 Grand Slams on the clay of Roland Garros, faces Hungary's Marton Fucsovics in his opener.
French Open and Wimbledon champion Carlos Alcaraz, the second seed, tackles 275th-ranked Hady Habib of Lebanon in opening round of the tournament, which starts on Saturday.
"Roland Garros is the most special place in the world of tennis for me," said 38-year-old Nadal, who was defeated in the first round of the French Open by Alexander Zverev last month during an injury-hit season.
"This year I was not able to spend a lot of time at Roland Garros so I am excited to be back here. It's another opportunity and a chance to enjoy every single moment."
Defending Olympic champion Zverev, seeded third, takes on Jaume Munar of Spain.
Russian fourth seed Daniil Medvedev, playing in Paris as a neutral following Moscow's invasion of Ukraine, will meet Rinky Hijikata of Australia.
Two-time singles gold medallist Andy Murray, who will end his career at the Olympics after almost two decades on tour, will only play doubles.
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